Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 4, Issue 11, Pages 2296-2303Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b603819k
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Diels - Alder cycloadditions of p-benzoquinone with 9R-(1-methoxyethyl) anthracene provides a 60 : 40 ratio of cycloadducts when heated at reflux in xylene. Mechanistic studies to explore the origins of this selectivity have shown that at lower temperatures the kinetic product predominates, giving a 96 : 4 ratio of cycloadducts.
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