Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 4, Issue 17, Pages 3225-3227Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b609734k
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The iterative copper(I)-catalyzed cycloaddition ( rt or microwave) between an ethynyl alpha-C-mannoside and alkyl 6-azido-alpha-C-mannoside derivatives was suited to the ( 1,6)-ligation between alpha-D-mannose units through 1,4-disubstituted triazole bridges, thus resulting in the formation of linear oligomers ( 80 - 90% yield) with alternating triazole and mannose fragments up to a triazolo-pentamannose derivative.
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