Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 4, Issue 19, Pages 3553-3564Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b608028f
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In this perspective, an overview of our experiences on the application of samarium diiodide in organic synthesis for the preparation of amino acid and peptide analogues is presented. Three different carbon-carbon bond forming reactions are discussed, including side chain introductions, gamma-amino acid synthesis and acyl-like radical additions for the construction of C-C mimics of the peptidic bonds.
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