Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 4, Issue 5, Pages 942-952Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b517631j
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In the presence of a photomediator such as benzophenone, alkynes with electron-withdrawing groups react with cycloalkanes to give vinyl cycloalkanes. The reaction involves the regiospecific addition of a photochemically generated cycloalkyl radical to the b-carbon of the alkyne. The stereochemical outcome of the reaction depends on the nature of the photomediator and alkyne used.
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