Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 16, Issue 34, Pages 3444-3447Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b609555k
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Two new series of bent-core mesogenic dimers with structurally different types of carbosilane units show broad regions of polar smectic phases with a transition from antiferroelectric to surface-stabilized ferroelectric switching with increasing length of the spacer units. A non-classical organization of the molecules in SmCsPF layer stacks with SmCaPA interfaces is proposed and based on this the switching properties and the formation of dark conglomerate phases are explained.
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