Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 4, Issue 11, Pages 2097-2099Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b605871j
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The bifunctional thiourea - tertiary amine derivatives of simple chiral diamines serve as highly enantioselective catalysts for the Michael addition of alpha-substituted cyanoacetates to vinyl sulfones, giving an efficient protocol for the construction of an all-carbon substituted quaternary stereocentre.
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