Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 8, Issue 48, Pages 5629-5632Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b615127b
Keywords
-
Ask authors/readers for more resources
The lithium solvation in (1 - x)(EMI-TFSI), xLiTFSI ionic liquids where EMI+ is the 1-ethyl-3-methylimidazolium cation and TFSI- the bis(trifluoromethanesulfonyl)imide anion, is shown by Raman spectroscopy to involve essentially [Li(TFSI)(2)](-) anionic clusters for 0 < x < 0.4, but addition of stoichiometric amounts of solvents S such as oligoethers changes the lithium solvation into [Li(S)(m)](+) cationic clusters; the lithium transference number in TFSI- based ionic liquid electrolytes for lithium batteries should thus be strongly improved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available