Journal
DALTON TRANSACTIONS
Volume -, Issue 37, Pages 4499-4505Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b606661e
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- Engineering and Physical Sciences Research Council [EP/C006763/1] Funding Source: researchfish
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A series of N-alkyldithiocarbamato complexes [M(S2CNHR)(2)] (M= Cd( II), Zn( II); R = C2H5, C4H9, C6H13, C12H25) have been synthesised and characterized. The decomposition of these complexes to sulfates has been investigated, and a mechanism proposed. The structures of [Zn(S(2)CNHHex)(2)], [Cd((SO4)(2)(NC5H5)(4))](n) and [Cd((SO4)(2)(NC5H5)(2)(H2O)(2))](n) have been determined by X-ray single crystal method. The cadmium complex [Cd(S2CNHC12H25)(2)] and zinc complex [Zn(S2CNHC6H13)(2)] were used as single-source precursors to synthesize CdS and ZnS nanoparticles, respectively. The synthesis of CdS nanoparticles was carried under various thermolysis conditions and changes in the shape of derived nanoparticles were studied by transmission electron microscope (TEM).
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