Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 16, Issue 24, Pages 2387-2394Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b603704f
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Alternating triphenylamine-based copolymers poly[N-(4-sulfonatobutyloxyphenyl)-4,4'-diphenylamine-alt-1,4-phenylene] sodium salt (PTPOBS) and poly[N-(4-sulfonatophenyl)-4,4'-diphenylamine-alt-N-(p-trifluoromethyl)phenyl-4,4'-diphenylamine] sodium salt (PTFTS) were synthesized via palladium-catalyzed Suzuki coupling reaction. These polymers are soluble only in polar solvents, such as dimethyl sulfoxide ( DMSO) and a mixed solvent of methanol and N,N-dimethyl formamide (DMF), rather than in non-polar solvents such as toluene and xylene. The electrochemical and photophysical properties of the resulted copolymers were investigated. The HOMO levels of the polymers (-5.08 eV for PTPOBS and -5.24 eV for PTFTS) were close to the work function of PEDOT. The relatively high-lying LUMO levels (-2.21 eV for PTPOBS and -2.24 eV for PTFTS) revealed that they had good electron-blocking capabilities. Devices with a PTPOBS or PTFTS layer inserted between ITO or PEDOT and of red and green-emitting polymers showed lower turn-on voltages and enhanced efficiency compared with the reference devices composed of bare ITO or ITO/PEDOT as anode. These polymers can be used as an independent hole-transport/electron-blocking layer or in combination with a PEDOT layer for fabrication of multilayer devices without intermixing with the subsequent EL layer by solution processing in full-color display applications.
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