Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 632, Issue 12-13, Pages 1950-1952Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.200600145
Keywords
yttrium; catalysis; polymerization
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Yttrium dialkyl complexes were prepared for three different 2,6-diisopropylphenyl-substituted benzamidinate ligands. The electron-donating ability of the parent ligand (L1) was decreased by a pentafluorophenyl backbone substituent (L2), and enhanced by addition of a pendant Lewis base (L3). The corresponding cationic monoalkyl species were generated and compared in catalytic ethene polymerization.
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