Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 9, Issue 1, Pages 86-89Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2005.10.005
Keywords
copper(II) complex; one-dimensional polymer; crystal structure; magnetic property
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One-dimensional copper(II) polymers [(CU4L2)(NO3)(4)]n (1) and [(Cu4L2)Cl-4](n) (2) (H2L = salicylaldehyde-2-pyridinecarboxyl-hydrazone) were achieved via self-assembly. The (CuCu)-Cu-... separations were ca. 2.90 and 4.75 angstrom for the phenoxide oxygen bridged pair and the N-N bridged pair with antiferromagnetic spin exchanges between Cu(II) ions. (c) 2005 Elsevier B.V. All rights reserved.
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