Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 348, Issue 9, Pages 1063-1070Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200606025
Keywords
Heck reaction; heterogeneous catalysis; immobilization; palladium; semiconductors; sulfur
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We have developed a method for preparing a recyclable and environmentally benign organo-palladium catalyst for the Heck reaction supported on sulfur-terminated gallium arsenide(001). This three-component catalyst, {Pd}-S-GaAs(001), exhibited high stability and activity, furthermore. it tolerated reuse in 10 runs of the Heck reaction (average yield, 97%) under aerobic conditions. The sulfur layer was very important to stabilize this catalyst. Only trace amounts of Pd were leached from this catalyst to the reaction mixture, as measured by ICP-mass. The valence of immobilized Pd was zero by XPS spectrometry.
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