Journal
MACROMOLECULAR SYMPOSIA
Volume 242, Issue -, Pages 49-54Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/masy.200651008
Keywords
barium titanate; electrorheological fluid; polyaniline; shear stress
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As organic/inorganic composites having attracted much attention due to their heterogeneous physical properties, conducting polyaniline (PANI) and barium titanate (BaTiO3) which possesses large electronic resistance and excellent dielectric strength, were utilized to synthesize PANI/BaTiO3 hybrid which is applicable for an electrorheological (ER) material via 'in-situ' oxidative polymerization. Physical properties of the obtained PANI/BaTiO3 composites were characterized via Fourier-transform infrared spectra (FT-IR), thermogravimetry analysis (TGA), and scanning electron microscopy (SEM). The ER behaviors were investigated via a rotational rheometer, and their shear stresses were fitted using our previously proposed rheological equation of state.
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