Journal
GREEN CHEMISTRY
Volume 9, Issue 12, Pages 1287-1291Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b711965h
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The palladium complex of the new disulfonated 9-(3-phenylpropyl)9'-PCy2-fluorene ligand is a highly active catalyst for aqueous Suzuki coupling reactions of N- heterocyclic chlorides and N-heterocyclic boronic acids; catalyst loadings of 0.02-0.1 mol% of Pd and two equiv. of phosphine result in the near quantitative formation of the respective coupling products at 100 degrees C.
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