Synthesis, growth and characterization of single crystals of pure and thiourea doped L-glutamic acid hydrochloride

L (+)Glutamic acid hydrochloride [HOOC (CH2)(2)CH(NH2) COOH center dot HCl], a monoamino dicarboxylic acid salt of L-Glutamic acid was synthesized and the synthesis was confirmed by FTIR analysis. Solubility of the material in water was determined. Pure and Thiourea doped L-Glutamic acid hydrochloride crystals were grown by low temperature solution growth using solvent evaporation technique. XRD, UV-Vis-NIR analyses were carried out for both pure and thiourea doped crystals. The crystals were qualitatively analyzed by EDAX analysis and the presence of thiourea was confirmed. The cell parameters of L-Glutamic acid hydrochloride have been determined as a = 5.151 angstrom, b = 11.79 angstrom, c = 13. 35A by X-ray diffraction analysis and it crystallizes in orthorhombic space group P2(1)2(1)2(1). UV-Vis-NIR spectra analysis showed good optical transmission in the entire visible region for both pure and doped crystals. Micro hardness of both pure and doped crystals has been determined using Vickers micro hardness tester. The SHG efficiencies of both pure and doped crystals were determined using Kurtz powder test and pure L-Glutamic acid hydrochloride crystal was found to possess better efficiency than thiourea doped L-Glutamic acid hydrochloride crystals. (c) 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.