Journal
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
Volume 18, Issue 4, Pages 728-732Publisher
SOC BRASILEIRA QUIMICA
DOI: 10.1590/S0103-50532007000400010
Keywords
arsenic; sediment; slurry sampling; hydride generation; atomic absorption; spectrometry
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A simple and robust method for the determination of arsenic in sediments by hydride generation atomic absorption spectrometry (HG-AAS) using slurry sampling is proposed. Aqua regia (5% v/v) and hydrofluoric acid (1% v/v) were mixed with an aliquot of the sediment with particle size of 50 mu m in an ultrasonic bath for 30 min. The slurry was allowed to stand for 48 h for an effective extraction of the analyte to the aqueous phase. The final volume of the slurry was made up with HCl 1mol L-1. A NaBH, solution stabilized with NaOH was used as reducing agent. The arsine was transported to the quartz T-tube heated at 900 degrees C for detection. Five certified reference materials of sediment were analyzed and the obtained concentrations were in good agreement with the certified values, according to the t-test for a 95% confidence level with RSD (relative standard deviation) lower than 13%. The limit of detection (LOD) in the sample was 0.6 mu g g(-1). The proposed procedure for arsenic determination in sediment is precise, accurate and adequate for the environmental samples routine analyses.
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