Journal
ACCOUNTS OF CHEMICAL RESEARCH
Volume 40, Issue 4, Pages 275-286Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ar050199q
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- NIGMS NIH HHS [GM 35249] Funding Source: Medline
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM035249] Funding Source: NIH RePORTER
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Organotrifluoroborates represent an alternative to boronic acids, boronate esters, and organoboranes for use in Suzuki-Miyaura and other transition-metal-catalyzed cross-coupling reactions. The trifluoroborate moiety is stable toward numerous reagents that are often problematic for other boron species. Consequently, remote functional groups within the organotrifluoroborates can be manipulated, while retaining the valuable carbon-boron bond.
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