Multirotations of (Anilinium)([18]Crown-6) supramolecular cation structure in magnetic salt of [Ni(dmit)(2)](-)

A solid-state dynamic supramolecular structure consisting of (anilinium)([18]crown-6) was arranged as the cation in a salt of [Ni(dmit)2](-)(dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate). With the ammonium moiety of anilinium located within the cavity of [18]crown-6, a hydrogen-bonded supramolecular. structure is formed, with an orthogonal arrangement between the a plane of anilinium and the mean 06 plane of [18]crown-6. In this supramolecular cation, both anilinium and [18]crown-6 act as dynamic units with different rotational modes in the solid state. The uniform stacks of cations form an antiparallel arrangement, thus producing a layer structure. Sufficient space for the 180 degrees flip-flop motion of the phenyl ring and the rotation of [18]crown-6 was observed in the cation layer. Thermally activated 180 degrees flip-flop motions, with a frequency of 6 MHz at room temperature and an activation energy of 31 kJmol(-1), were confirmed by temperature-dependent H-2 NMR spectra of ([D-5]anilinium)([18]crown-6)[Ni(dmit)(2)]. A double-minimum potential for the molecular rotation of anilinium, with a barrier of approximately 40 kJmol(-1), was indicated by ab initio calculations. The wideline H-1 NMR spectra indicated a thermally activated rotation of [18]crown-6 at temperatures above 250 K. Therefore, multiple molecular motions of the 180 degrees flip-flop motion of the phenyl ring and the rotation of [18]crown-6 occur simultaneously in the solid state. The temperature-dependent dielectric constants revealed that the molecular motion of [1,8]crown-6, other than the flip-flop motion, dominates the dielectric response in the measured temperature and frequency range.