Corrosion protection of sol-gel coatings doped with an organic corrosion inhibitor: Chloranil

Hybrid sol-gel films have been prepared with diethoxydimethylsilane (DEODMS), methyltriethoxysilane (MTEOS) as a source of hydrolysable silane and tetra-propoxyzirconium (TPOZ) as a source of hydrolysable zirconium. In order to improve corrosion protection, an organic corrosion inhibitor: tetrachloro-p-benzoquinone (chloranil), has been incorporated into the sol-gel matrix. The effect of chloranil, added with various concentrations from 3 to 12 x 10(-4) M, on the sol-gel film morphology and composition has been examined by atomic force microscopy (AFM) and glow discharge optical emission spectroscopy (GDOES), respectively. Addition of high additive concentrations (> 9 x 10(-4) M) strongly disorganised the sol-gel network. The anticorrosion properties of the doped sol-gel films have been characterised by electrochemical impedance spectroscopy (EIS) in chloride solution and have been compared to salt spray observations. Chloranil additions (< 9 x 10(-4) M) have significantly increased the corrosion protection of the sol-gel layers for a long term. (c) 2006 Elsevier B.V. All rights reserved.