Journal
POLYMER JOURNAL
Volume 39, Issue 12, Pages 1360-1364Publisher
SOC POLYMER SCIENCE JAPAN
DOI: 10.1295/polymj.PJ2007069
Keywords
network formation; interlocked copolymer; copolymerization; 1,2-dithiane; lipoic acid; Zn(acetate)(2); ionomeric bonding
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Network formation of interlocked copolymer obtained from the thermal ring-opening copolymerization of 1,2-dithiane (DT) and liopic acid (LPA) was investigated by the reaction of the poly(LPA-co-DT) and Zn(acetate)(2). From the IR spectra of the reaction products, the reaction was induced readily to make a enough high degree of cross-linking in which the cross-linking points are polycatenane using a bifunctional metal salts by effective an ionomeric network. The cross-linking reaction of the precursor copolymer gave more thermo-stable product by the formation of the enough high degree of cross-linking structure.
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