Journal
COORDINATION CHEMISTRY REVIEWS
Volume 251, Issue 17-20, Pages 2280-2291Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2006.11.006
Keywords
C-H activation; alpha-bond metathesis; oxidative additions; reaction mechanisms
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The metathesis reactions of LnMR + R '-H -> LnMR ' + R-H are important fundamental reactions in organometallic chemistry and catalysis. In this article, we reviewed the current understanding of the reactions from a theoretical point of view. Selected examples of the reactions involved in catalysis were discussed. (C) 2006 Elsevier B.V. All rights reserved.
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