Pressure leaching of sulfidized chalcopyrite in sulfuric acid-oxygen media

The recovery of copper from chalcopyrite concentrates by leaching is difficult due to the slow dissolution kinetics of this mineral in most leaching media. However, recovery of copper from sulfidized chalcopyrite (a mixture of CuS and FeS(2)) by leaching is faster and could be selective depending on the leaching media. In this paper, the result of an investigation on the H(2)SO(4)-O(2) pressure leaching of sulfidized chalcopyrite is presented. The variables considered in the study were stirring speed, concentration of sulfuric acid, temperature, and partial pressure of oxygen. The experimental data indicated that stirring speed over 500 rpm and sulfuric acid concentration over 0.1 M had very little effect on the leaching rate. An increase in temperature from 90 to 108 degrees C increased both copper and iron dissolution; however, further increase to 120 degrees C affected negatively the copper dissolution. Oxygen partial pressure was found to be the main variable that controls the copper/iron selectivity of the leaching. An increase in oxygen partial pressure increased significantly the rate of copper dissolution but deteriorated the copper/iron selectivity. The analysis for elemental sulfur of the solid leach residues indicated that most of the copper sulfide sulfur in the sulfidized concentrate oxidized to elemental sulfur. (C) 2006 Elsevier B.V. All rights reserved.