Journal
FARADAY DISCUSSIONS
Volume 135, Issue -, Pages 55-78Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b605404h
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The Source Function ( SF) analysis is applied to a set of saturated [M-2(CO)(x), M = Mn, Fe, Co, Ni, x = 10, 9, 8, 7] and unsaturated [Co-2(CO)(x), x=8-5] binuclear 3d metal carbonyls, and to the M-2( formamidinate)(4) ( M = Nb, Mo, Tc, Ru, Rh, and Pd) binuclear 4d metal complexes, using ab initio electron densities. A description of the metal-metal (M-M) bonding closely related to that provided by the localization/delocalization indices is afforded. The agreement persists even when the M-M bond is lacking and the internuclear M-M midpoint is taken as a reference point for evaluating the SF contributions. However, use of the local form of the SF unveils interesting differences in how the charge density originates at the M-M midpoint when the system is metal metal bonded or not. Most of the topological indices conventionally adopted to describe M-M bonds fail in reproducing the expected chemical trends for the set of investigated systems, with the adimensional vertical bar V-b vertical bar/G(b) ratio and the del(2)rho(b) value being particularly inadequate.
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