Investigation of adsorption and inhibition effects of some novel anil compounds towards mild steel in H2SO4 solution: Electrochemical and theoretical quantum studies

A novel anil compounds, 1-{(Z)-[(3,5dimethylphenyl)imino]methyl}naphthalen-2-ol (HNMA) and 5-(diethylamino) -2- {(Z)- [(3,5-dimethylphenyl)imino] methyl} phenol (DMSMA), were prepared and characterized on the basis of elemental analyses, X-ray, H-1 NMR, C-13 NMR, UV-Vis and IR spectral data. Their inhibiting performance for mild steel in 0.5 M H2SO4 solution was evaluated by a series of techniques including potentiodynamic polarization, electrochemical impedance spectroscopy, scanning electronic microscope (SEM), energy-dispersive X-ray spectroscopy (EDX) and theoretical calculations. Findings show that HNMA and DMSMA act as good inhibitors, and their inhibition efficiency increases with increasing their concentration. Polarization data suggested that the Schiff bases molecules used as mixed type inhibitors. Impedance measurements indicating that the corrosion reaction is controlled by charge transfer process. The adsorption of HNMA and DMSMA on the metal surface was found to obey Langmuir adsorption isotherm. Furthermore, theoretical study gives insightful explanations of the inhibition mechanism. (C) 2015 Elsevier B.V. All rights reserved.