Silicic volcanism in Iceland: Composition and distribution within the active volcanic zones

Silicic volcanic rocks within the active volcanic zones of Iceland are mainly confined to central volcanoes. The volcanic zones of Iceland can be divided into rift zones and flank zones. Each of these zones contains several central volcanoes, most of which have produced minor amounts of silicic rocks. The silicic rocks occur as lavas and domes or as tephra layers, welded tuffs and ignimbtztes, formed both in effusive and explosive eruptions. They tend to be glassy or very fine-grained, containing small amounts of phenocrysts. Plagioclase (andesine-oligoclase), anorthoclase or occasionally sanidine coexist with minerals such as augite, fayalite, pigeonite, orthopyroxene and magnetite. Quartz phenocrysts are exceedingly rare. Zoning of phenocrysts is limited and the pattern is variable. A set of 90 samples representing all active central volcanoes that have erupted silicic rocks was analysed for major- and trace-elements. The silicic rocks can be classified as dacites, trachytes, low-alkali rhyolites and alkalic rhyolites. Some of the trachytes and alkalic rhyolites are peralkaline (mostly comenditic). Trachytes and alkalic rhyolites are only found within the flank zones, while dacites and low-alkali rhyolites are mostly confined to the rift zones. The Icelandic rhyolites plot close to the thermal minimum in the granite system, while dacites and trachytes plot within the plagioclase field and towards the alkali feldspar temperature minimum. The silicic rocks are relatively Fe-rich and Ca-poor indicating low water pressure in the source. Trace element concentrations follow similar patterns in most central volcanoes. Exceptions are Torfajokull where silicic rocks display a negative correlation of Ba to Th and unusually high Th-contents, and the western flank zone where Ba-concentrations are highly variable. The ratios of different high field-strength elements are generally similar within each central volcano or region, which probably reflects different ratios in the source materials. Isotope systematics indicate that the silicic rocks are derived from older basaltic rocks similar to those from the same volcano, and that meteoric water has played a role in the genesis of the silicic rocks. Traditionally, the petrogenesis of silicic rocks in Iceland has been explained by various models of fractional crystallization or partial melting. The available data seems to be better explained by near-solidus differentiation than by near-liquidus differentiation. The silicic minimum melts can be extracted from the rigid framework of the near-solidus source by the process of solidification front instability or by deformation-assisted melt segregation. The source of the silicic rocks is within the intrusive complex beneath a central volcano rather than in a large, long-lived magma chamber. (c) 2006 Elsevier Ltd. All rights reserved.