Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 1, Pages 88-90Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b611265j
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PEP and aldolase mimicry is the key for a direct organocatalytic entry to precursors of ulosonic acids, biomolecules of enormous importance in biology, chemistry and medicine; in the key aldol reaction the dimethylacetal of pyruvic aldehyde is used as phosphoenolpyruvate (PEP) equivalent and the amino acid proline functions as an organocatalyst, imitating the enzyme.
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