4.7 Article

Cobalt-catalyzed intermolecular C-H amination with bromamine-T as nitrene source

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 44, Pages 4644-4646

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b710677g

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Cobalt, supported by porphyrin ligands, is capable of catalyzing intermolecular nitrene insertion of sp(3) C-H bonds with bromamine-T as the nitrene source, forming the desired tosyl-protected amines with NaBr as the by-product.

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