4.7 Article

Supported ionic liquid catalyst (Pd-SILC) for highly efficient and recyclable Suzuki-Miyaura reaction

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 27, Pages 2838-2840

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b704098a

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Highly efficient Suzuki-Miyaura coupling of aryl halides with arylboronic acid was realized in 50% aqueous ethanol at room temperature employing Pd(OAc)(2) immobilized in diethylaminopropylated (NDEAP) alumina pores with the aid of [bmim]PF6, which enabled recycle use up to five times in 95% average yield and turnover number of two million.

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