4.8 Article

Chiral N-heterocyclic carbenes in natural product synthesis: Application of Ru-catalyzed asymmetric ring-opening/cross-metathesis and Cu-catalyzed allylic alkylation to total synthesis of baconipyrone C

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 46, Issue 21, Pages 3860-3864

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.200700501

Keywords

allylic alkylation; asymmetric catalysis; natural products; N-heterocyclic carbenes; olefin metathesis

Funding

  1. NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM047480, R37GM047480, R29GM047480] Funding Source: NIH RePORTER
  2. NIGMS NIH HHS [GM-47480] Funding Source: Medline

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