4.7 Article

Twisted oxygen-containing oligosilanes-unprecedented examples of sigma-n mixed conjugated systems

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 18, Pages 1810-1812

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b618438c

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Twisting the silicon backbone conformation in oxygen containing oligosilanes towards dihedral angles of 120 - 130 degrees either by intramolecular hydrogen bonding or incorporation into a covalently bonded ring system effectively extends the delocalization of electrons in these sigma - n mixed conjugated systems.

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