4.7 Article

Heteronuclear Mn-Ca/Sr complexes, and Ca/Sr EXAFS spectral comparisons with the oxygen-evolving complex of photosystem II

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 15, Pages 1538-1540

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b701355h

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Funding

  1. NIGMS NIH HHS [R01 GM055302, R56 GM055302, GM 55302] Funding Source: Medline
  2. NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM055302, R56GM055302] Funding Source: NIH RePORTER

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Heterometallic Mn-Ca and Mn-Sr complexes have been prepared and employed as model complexes for Ca and Sr EXAFS spectral comparisons with the Oxygen-Evolving Complex (OEC) of Photosystem II (PS II); these have revealed similarities that support the presence of at least one O atom bridge between the Mn and Ca/Sr in the OEC.

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