Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 5, Pages 486-488Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b617700j
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The U(IV) linear pentacyano metallocene [U(C5Me5)(2)(CN)(5)] [NEt4](3) reacted with 2 molar equivalents of pyridine N-oxide in THF or acetonitrile to give the U( VI) complex [UO2(C5Me5)(CN)(3)][NEt4](2), the first uranyl species containing the cyclopentadienyl ligand; the crystal structure revealed that the steric effects of the (C5Me5) ligand force the {UO2}(2+) ion to deviate from linearity.
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