Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 40, Pages 4107-4109Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b708479j
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The solvothermal reaction of Zn( II) and 4,4'- oxybis( benzoic acid) in the presence of anhydrous ethanol leads to the generation of a novel 3D chiral coordination polymer with triple helical chains; the resulting crystals were not a racemic mixture but had an enantiomeric excess, which was confirmed by measuring the optical rotation of bulk samples using solid state vibrational circular dichroism ( VCD).
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