Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 35, Pages 3664-3666Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b707840d
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The C-F bond activation of fluoropyridines by [Rh(SiPh3)(PMe3)(3)] afforded Rh(I) fluoropyridyl complexes of the type [Rh(Ar-F)(PMe3)(3)] with concomitant formation of fluorotriphenylsilane; subsequent treatment with bis-catecholatodiboron yielded fac-[Rh(Bcat)(3)(PMe3)(3)] and the free fluoropyridyl boronate esters (Ar(F)Bcat).
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