Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 3, Pages 272-274Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b613416e
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We have developed efficientcopper-catalyzed additions of P(O)H compounds to alkynes, and the reactions provided the regio- and stereoselective E-alkenylphosphine oxides under catalysis of the commercially available and inexpensive copper catalyst system CuI/ethylenediamine. This finding is the first example of copper-catalyzed hydrophosphinylation of alkynes to synthesize alkenylphosphine oxides.
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