Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 38, Pages 3945-3947Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b710681e
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- Engineering and Physical Sciences Research Council [EP/E025080/1] Funding Source: researchfish
- EPSRC [EP/E025080/1] Funding Source: UKRI
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Addition of AlMe3 to commercial THF solutions of RZnX (R=5 aryl, functionalised aryl, vinyl; X = Br, I) simultaneously promotes Schlenk equilibria ( leading to competent nucleophiles) and the formation of an Al-Zn-ligand catalyst delivering 80-90% ee for (ArCH)-C-1(OH)Ar-2 formation from aldehydes.
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