4.7 Article

Formation of two (6,3) networks showing structural diversity, Borromean topology and conformational chirality in the same crystal

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 41, Pages 4242-4244

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b709118d

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Reaction of two tripodal ligands, 2,4,6-tris(4-((2-methyl-benzimidazol-1-yl) methyl) phenyl)- 1,3,5-triazine (L-1) and 1,3,5-tris( 4(( 2-methyl- benzimidazol-1-yl) methyl) phenyl) benzene ( L 2), with AgSbF6 led to formation of two types ( 6,3) networks in one single crystal, of which one is three-fold Borromean topologically entangled while the other is independent, showing the same chirality and sandwiched Borromean stacking.

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