Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 13, Pages 1349-1351Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b700909g
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Fourfold symmetric zinc-octaethylporphyrin (OEP) has been incorporated in the holes of the hexagonal molecular network generated by thermal dehydrogenation of 4,9-diaminoperylenequinone3,10- diimine (DPDI) on a Cu(111) surface and displayed hindered rotation; the reorganization between the potential minima, a rotation-libration, which is characterized by an activation energy of E-D=0.17 +/- 0.03 eV, has been monitored in the STM tunnelling currents as a bi-state ''switching''.
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