Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 37, Pages 3805-3813Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b701128h
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In this review, we describe the combination of enzymatic polymerisation and controlled free radical polymerisation in supercritical carbon dioxide. This combination facilitates the preparation of a range of block and graft copolymers, some of which cannot easily be obtained by conventional polymer synthesis. Biocatalysis in polymer science provides significant new opportunities and will open up a very broad range of new polymeric materials.
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