Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 13, Issue 2, Pages 582-591Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200600502
Keywords
carbene ligands; cross-coupling; nickel; phosphane ligands; synthetic methods
Categories
Ask authors/readers for more resources
Nickel(II) complexes of bidentate N-heterocyclic carbene (NHC)/ phosphane ligand L were prepared and structurally characterized. Unlike palladium, which forms [PdCl2(L)], the stable nickel product isolated is the ionic [Ni(L)(2)]Cl-2. These Ni-II complexes are highly robust in air. Among different N-substituents on the ligand framework, the nickel complex of ligand L bearing N-1-naphthylmethyl groups (2a) is a highly effective catalyst for Suzuki cross-coupling between phenylboronic acid and a range of aryl halides, including unreactive aryl chlorides. The activities of 2a are largely superior to those of other reported nickel NHC complexes and their palladium counterparts. Unlike the previously reported [NiCl2(dppe)] (dppe= 1,2-bis(diphenylphosphino)ethane), 2a can effectively catalyze the cross-coupling reaction without the need for a catalytic amount of PPh3, and this suggests that the PPh2 functionality of hybrid NHC ligand L can partially take on the role of free PPh3. However, for unreactive aryl chlorides at low catalyst loading, the presence of PPh3 accelerates the reaction.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available