4.6 Article

Catalytic applications of metal nanoparticles in imidazolium ionic liquids

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 13, Issue 1, Pages 32-39

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200601438

Keywords

heterogeneous catalysis; ionic liquids; nanostructures; supramolecular chemistry; transition metals

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Metal nanoparticles (MNPs) with a small diameter and narrow size distribution can be prepared by H, reduction of metal compounds or decomposition of organometallic species dissolved in ionic liquids (ILs). MNPs dispersed in ILs are catalysts for reactions under multiphase conditions. These soluble MNPs possess a pronounced surfacelike rather than single-site like catalytic properties. In other cases the MNPs are not stable and tend to aggregate or serve as reservoirs of mononuclear catalytically active species.

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