Journal
DALTON TRANSACTIONS
Volume -, Issue 46, Pages 5372-5375Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b715197g
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The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the heterocyclic framework; the presence of axial chirality was predicted by means of DFT calculations and experimentally verified by chiral HPLC analysis, derivatization experiments as well as temperature dependent P-31{H-1} NMR spectroscopy.
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