Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 13, Issue 5, Pages 1539-1546Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200600897
Keywords
chelates; dihydrogen complexes; hydrides; phosphine ligands; ruthenium
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The synthesis and characterisation of nonclassical ruthenium hydride complexes containing bidentate PP and tridentate PCP and PNP pincer-type ligands are described. The mononuclear and dinuclear ruthenium complexes presented have been synthesised in moderate to high yields by the direct hydrogenation route (one-pot synthesis) or in a two-step procedure. In both cases [Ru(cod)(metallyl)(2)] served as a readily available precursor. The influences of the coordination geometry and the ligand framework on the structure, binding, and chemical properties of the M-H, fragments were studied by X-ray crystal structure analysis, spectroscopic methods, and reactivity towards N-2, D-2, and deuterated solvents.
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