Ferromagnetic coupling in trinuclear, partial cubane Cu-II complexes with a mu(3)-OH core: Magnetostructural correlations

Three new trinuclear copper(II) complexes, [(CuL1)(3)(mu(3)-OH)][ClO4](2)center dot 3H(2)O (1), [(CuL2)(3)(mu(3)-OH)]-[ClO4](2)center dot H2O (2), and [(CuL2)(3)(mu(3)-OH)][ClO4](2)center dot H2O (3) have been synthesized from the three tridentate Schiff bases HL1, HL2, and HL3 (HL1= 6-aminomethyl-3-methyl-1-phenyl-4-aza- hex-2-en-1-one, HL2 = 6-aminoethyl-3-methyl-1 -phenyl-4-azahex-2-en-1-one, and HL3 = 6-aminodimethyl-3-methyl-1-phenyl-4-azahex-2-en-1-one). They have been characterized by X-ray crystallography and IR and UV spectroscopy, and their magnetic properties have been investigated. All the compounds contain a partial cubane [Cu3O4] core consisting of the trinuclear unit [(CuL)(3)(mu(3)-OH)](2+), perchlorate ions, and water molecules. In each of the complexes, the copper atoms are five-coordinate with a distorted square-pyramidal geometry except complex 1, in which one of the Cull of the trinuclear unit is weakly coordinated to one of the perchlorate ions. Magnetic measurements performed in SQUID MPMS-XL7 using polycrystalline samples at an applied field of 2 kOe indicate a global intramolecular ferromagnetic coupling. Magnetostructural correlations have been calculated on the basis of theoretical models without symmetry restriction. Continuous shape measurements are an appropriate tool for establishing the degree of distortion of the Cu-II from squareplanar geometry. Structural, theoretical, and experimental magnetic data indicate that the higher the degree of distortion, the greater the ferromagnetic coupling.