Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 5, Issue 21, Pages 3407-3417Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b711499k
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Catalytic asymmetric reduction reactions have long been the preserve of the transition metal catalyst. Inspired by the myriad efficient enzyme-catalysed reduction reactions routine in biological systems, chemists have recently begun to design chiral metal-free organocatalysts that employ synthetic dihydropyridine NADH analogues as the hydride source with impressive results. Recent developments in this burgeoning field are discussed.
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