4.6 Article

An unusual stereoselectivity in the anomeric substitution with carbamates promoted by HNTf2

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 5, Issue 3, Pages 431-434

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b615725d

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An unexpected stereoselective anomeric substitution with carbamates promoted by HNTf2 is described here. Our experiments suggest that the observed diastereoselectivity is a result of thermodynamic equilibration of protonated N-acyl aminals.

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