Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 5, Issue 3, Pages 431-434Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b615725d
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An unexpected stereoselective anomeric substitution with carbamates promoted by HNTf2 is described here. Our experiments suggest that the observed diastereoselectivity is a result of thermodynamic equilibration of protonated N-acyl aminals.
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