Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 5, Issue 19, Pages 3126-3134Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b710794c
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In the presence of a catalytic amount of Bi(OTf)(3)center dot 4H(2)O, aldehydes together with amines react with silyl enolates to afford the corresponding Mannich-type adducts smoothly. A wide variety of silyl enolates derived from ketones, as well as esters and thioesters, react rapidly to afford the beta-amino ketones or the beta-amino esters in high yields (up to 94%).
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