Journal
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Volume 87, Issue 2, Pages 539-544Publisher
SPRINGER
DOI: 10.1007/s10973-005-7295-2
Keywords
adiabatic calorimetry; heat capacity; low temperature; n-butanol; water
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The molar heat capacities of the binary mixture composed of water and n-butanol were measured with an adiabatic calorimeter in the temperature range 78-320 K. The functions of the heat capacity with respect to thermodynamic temperature were established. A glass transition, solid-solid phase transition and solid-liquid phase transition were observed. The corresponding enthalpy and entropy of the solid-liquid phase transition were calculated, respectively. The thermodynamic functions relative to a temperature of 298.15 K were derived based on the relationships of the thermodynamic functions and the function of the measured heat capacity with respect to temperature.
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