Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 5, Issue 2, Pages 226-228Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b614786k
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A pyrene - terpyridine - Zn conjugate has been synthesized and characterized, where Zn2+ acts as an electron acceptor to enhance molecular ICT with a large emission red-shift (> 100 nm). It showed a ratiometric fluorescence change upon addition of phosphate anions in buffered aqueous solution. The selective response to phosphates or pyrophosphates involved ICT and ligand competition processes.
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