4.6 Article

On the enantioselective olefin epoxidation by doubly bridged biphenyl azepine derivatives - mixed tropos/atropos chiral biaryls

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 5, Issue 3, Pages 501-506

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b615797a

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Diastereomeric doubly bridged biphenyl azepines, atropos at 20 degrees C and tropos at 80 degrees C, are precursors to effective iminium organocatalysts that are employed in the enantioselective epoxidation of prochiral olefins ( up to 85% ee).

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